Quantrinas написал(а):
Электроны там вообще прыгают куда хотят, а вот протонам это труднее.
Надо полагать что это так но... большинство публикаций по преносу частиц между парами в ДНК - по протону а не по электрону
В этом нет противоречия ?
Charge transfer and environment effects responsible for characteristics of DNA base pairing
Ab initio molecular orbital calculations on DNA base pair radical ions: effect of base pairing on proton-transfer energies, electron affinities, and ionization potentials
Investigation of proton transfer within DNA base pair anion and cation radicals by density functional theory (DFT)
Ab initio molecular orbital calculations of DNA bases and their radical ions in various protonation states: evidence for proton transfer in GC base pair radical anions
DNA mutations induced by proton and charge transfer in the low-lying excited singlet electronic states of the DNA base pairs: A theoretical insight
Proton Transfer in DNA Base Pairs
Double Proton Transfer: From the Formamide Dimer to the Adenine.cntdot..cntdot..cntdot.Thymine Base Pair
Effects of protonation on proton transfer processes in Watson–Crick adenine–thymine base pair
Effects of protonation on proton-transfer processes in guanine–cytosine Watson–Crick base pairs
Electron correlated and density functional studies on hydrogen-bonded proton transfer in adenine-thymine base pair of DNA
Double proton transfer in the isolated and DNA-embedded guanine-cytosine base pair
Double-proton transfer in adenine-thymine and guanine-cytosine base pairs. A post-Hartree-Fock ab initio study
A DNA Sensor for Sequencing and Mismatches Based on Electron Transport Through Watson–Crick and Non-Watson–Crick Base Pairs
Proton transfer in the adenine-thymine base pair
The origin of spontaneous point mutations in DNA via Lwdin mechanism of proton tunneling in DNA base pairs: Cure with covalent base pairing*
Spontaneous DNA Mutations Induced by Proton Transfer in the Guanine Cytosine Base Pairs: An Energetic Perspective
Theoretical study of proton transfers between base pairs of DNA